Afaik, inside App.config and Web.config you have to use the NameValue style:
Code:
<?xml version="1.0" encoding="utf-8" ?>
<configuration>
<configSections>
<section name="nhibernate" type="System.Configuration.NameValueSectionHandler, System, Version=1.0.5000.0, Culture=neutral, PublicKeyToken=b77a5c561934e089" />
</configSections>
<nhibernate>
<add
key="hibernate.connection.provider"
value="NHibernate.Connection.DriverConnectionProvider"
/>
<add
key="hibernate.dialect"
value="NHibernate.Dialect.MsSql2000Dialect"
/>
...
</nhibernate>
<!-- other app specific config follows -->
</configuration>