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Are there any other more mature products that offer simular functionality?
Unlike the Java world, where hibernate pretty much has a lock on the ORM market (or so I'm told, I'm not much of a Java guru), there are many, many ORM tools in the .net world, some of which are older and more widely used than NHibernate. A couple of links illustrate the problem:
http://www.theserverside.net/news/thread.tss?thread_id=29914
http://sharptoolbox.com/Pages/Category74089b0a-1105-4389-b1db-eedf27e20cfb.aspx
After evaluating several of what we thought were the leading contenders as well as NHibernate, my company decided to use NHibernate, partly because, like you, we have experience with hibernate that translates nicely, and partly because NHibernate just seemed like a better product than almost all of the other ORM tools we tried, commercial or no. After a few months using it, I'm still convinced we made the right decision.